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The molecule H2CO contains: (note, consider all the bonds of this molecule)


A) 2 s bonds and 2 p bonds
B) 1 s and 3 p bonds
C) 3 s and 2 p bonds
D) 2 s and 1 p bond
E) 3 s and 1 p bond

F) None of the above
G) A) and B)

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The C - C sigma bond in HCCCl is most reasonably formed from overlap of:


A) a sp2 orbital on HC carbon atom and a sp2 orbital on CCl carbon atom.
B) a sp orbital on HC carbon atom with a sp orbital on CCl carbon atom.
C) a sp2 orbital on HC carbon atom with a sp orbital on CCl carbon atom.
D) a sp3 orbital on HC carbon atom with a sp3 orbital on CCl carbon atom.
E) none of these

F) A) and D)
G) A) and E)

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Three statements are given below. Pick the best answer. I. BCl3 is a trigonal planar molecule. II. SF6 is an octahedral molecule. III. PH3 is a trigonal planar molecule.


A) I and II are correct, III is not
B) I and III are correct, II is not
C) II and III are correct, I is not
D) all are true
E) only I is true

F) A) and B)
G) B) and E)

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Which of the following molecules is(are) polar? I. SO2 (angular) II. OF2 (angular) III. C S2 (linear)


A) I only
B) II only
C) III only
D) I and II
E) II and III

F) C) and E)
G) B) and C)

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What is the steric number with respect to the central sulfur atom in the Lewis structure for sulfur dioxide, SO2?


A) 2
B) 3
C) 4
D) 5
E) 6

F) All of the above
G) None of the above

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Pick the one statement listed below that is true .


A) The H - S - H angle in H2S is about 180 ° .
B) The Cl - P - Cl angles in PCl3 are all about 120 ° .
C) The F - Al - F angles in AlF3 are all about 120 ° .
D) The O - S - O angle in SO2 is 180 ° .
E) All 4 answers are false.

F) B) and E)
G) C) and D)

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How many unpaired electrons are present in B2 - ?


A) 1
B) 2
C) 3
D) 0
E) none of these

F) D) and E)
G) B) and E)

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What is the bonded atom lone pair arrangement with respect to the electrons around the central iodine atom in the species, IF41 - ?


A) Tetrahedral
B) Trigonal bipyramidal
C) See-Saw
D) Octahedral
E) Square base pyramid

F) A) and E)
G) B) and D)

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How many unpaired electrons are present in O2 - ?


A) 1
B) 2
C) 3
D) 0
E) none of these

F) A) and E)
G) A) and B)

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What is the electron configuration of He2+?


A) ( s ls) 2 ( s *ls) 1
B) ( s ls) 2
C) ( s ls) 2 ( s *ls) 2
D) ( s ls) 2 ( p ls) 1
E) none of these

F) None of the above
G) A) and C)

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Which of the following molecules would have a Lewis structure that most closely resembles CCl4, as well as having an identical bonded atom lone pair arrangement and an identical molecular shape?


A) SF4
B) XeF4
C) SiBr4
D) IF41 -
E) None of these

F) A) and D)
G) B) and C)

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Which of the following molecules is(are) non-polar ? I. XeF4 (square planar) II. CHCl3 (tetrahedral) III. SF4 (see-saw)


A) I only
B) I and II
C) I and III
D) II and III
E) All of these

F) None of the above
G) A) and B)

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The bonded atom lone pair arrangement about the nitrogen atoms in HNNH is:


A) trigonal planar.
B) tetrahedral.
C) trigonal bipyramidal.
D) octahedral.
E) none of these

F) C) and D)
G) A) and B)

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Which of the following molecules would have a Lewis structure that most closely resembles O3, as well as having an identical bonded atom lone pair arrangement and an identical molecular shape?


A) H2S
B) CO2
C) OCl2
D) SO2
E) KrF2

F) A) and B)
G) All of the above

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Which molecule from the list below is considered polar ? The molecular shape is listed in parenthesis.


A) NCl3 (trigonal pyramidal)
B) CO2 (linear)
C) CH4 (tetrahedral)
D) N2 (linear)
E) SO3 (trigonal planar)

F) C) and D)
G) B) and D)

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What is the steric number with respect to the central iodine atom in the Lewis structure for the species, IF41 - ?


A) 2
B) 3
C) 4
D) 5
E) 6

F) A) and D)
G) C) and E)

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What molecular shape is assumed by the four atoms in the nitrate anion, NO31 - ?


A) Angular
B) Linear
C) Trigonal planar
D) Trigonal pyramidal
E) T-shape

F) A) and B)
G) C) and E)

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What molecule listed below has a see-saw molecular shape?


A) XeF4
B) SF4
C) SiF4
D) CF4
E) ClF5

F) B) and C)
G) All of the above

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Which of the following molecules would have a Lewis structure that most closely resembles SiO2, as well as having an identical bonded atom lone pair arrangement and an identical molecular shape?


A) H2O
B) C S2
C) SCl2
D) SO2
E) XeF2

F) A) and C)
G) A) and B)

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What is the electron configuration of NO - ?


A) ( s 2s) 2 ( s *2s) 2 ( p 2p) 4 ( s 2p) 2
B) ( s 2s) 2 ( s *2s) 2 ( p 2p) 4 ( s 2p) 2 ( p *2p) 2
C) ( s 2s) 2 ( s *2s) 2 ( p 2p) 4
D) ( s 2s) 2 ( s *2s) 2 ( p 2p) 4 ( s 2p) 2 ( p *2p) 4
E) none of these

F) A) and B)
G) None of the above

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